OMS-2催化剂成型工艺研究及其在印染废水处理中的应用

以OMS-2粉体催化剂为基础,对催化剂进行挤出成型,考察粘结剂种类、粘结剂用量、润滑剂和孔结构改进剂用量、焙烧温度对成型催化剂机械强度的影响。得到最佳成型工艺条件为,粘结剂硅溶胶用量为OMS-2粉体催化剂质量的105%～110%、辅助粘结剂纳米ZrO_2用量为OMS-2粉体催化剂质量的30%～35%、润滑剂田菁粉用量为OMS-2粉体催化剂质量的2. 5%～3. 0%、孔结构改进剂柠檬酸用量为OMS-2粉体催化剂质量的5%～6%,焙烧温度450℃。成型后催化剂机械强度可达150 N·cm~(-1),满足工业化应用对催化剂强度的要求。将成型催化剂应用于催化湿式氧化印染废水处理,经过432 h活性评价时间,COD平均去除率约91. 6%,反应结束后催化剂结构完整,平均机械强度约144 N·cm~(-1),表现出良好的水热稳定性。     

基于斯特林制冷机的文物恒湿展柜设计及实验研究

博物馆文物保存过程中相对湿度对文物的影响尤其重要，因此针对目前小型展柜广泛采用的半导体制冷存在制冷量小的缺点，结合斯特林制冷机制冷量大、寿命长、安全可靠等优点，设计并搭建了一台基于斯特林制冷的文物恒湿展柜装置，实现对微环境中相对湿度的精确调节。将斯特林制冷机的冷头置于优化设计的水槽中用于控制水温，采用空气与水直接接触的方式控制展柜内空气湿度。结果表明：使用散热片以及小型循环水泵可以大幅提升冷头与水之间的换热效率；合理的风机控制策略可以有效提升展柜湿度调节速度，维持湿度稳定，降低系统能耗；展柜内的相对湿度在45.0%～65.0%之间连续可调，并能保持稳定。     

小庄煤矿地应力场分布规律实测与模拟研究

地应力场主要由自重应力场和构造应力场组成,是影响井下采掘工程活动最重要和最根本的因素,掌握矿井的地应力场分布规律,对整体提高矿井的经济效益和社会效益具有重要的意义。本文在小庄煤矿区域采用套空应力解除法进行地应力场测量,并采用三维应力场反演验证测量结果,从而得出了小庄煤矿的应力分布规律,为矿井动力现象的预测预防奠定了基础。     

Flame Retardancy and Mechanical Properties of Bio‐Based Furan Epoxy Resins with High Crosslink Density

This work outlines an interesting approach to bioepoxy resins from sustainable 2,5‐bis((oxiran‐2‐ylmethoxy)methyl)furan (BOF). The 3,3′‐diamino diphenyl‐sulfone (33DDS) and 4,4′‐diamino diphenyl‐sulfone (44DDS) are employed as hardeners. For comparison, petro‐based networks from diglycidyl ether of bisphenol A (DGEBA) are developed as well. The systematic analyses suggest that the BOF/DDS networks show higher crosslink densities and mechanical properties than DGEBA/DDS thermosets. Remarkably, an attractive multilayer tubular microstructure is fabricated in the BOF/44DDS thermosets, and it greatly enhances the mechanical performance. Apart from that, BOF/DDS composites exhibit excellent flame retardancy. Especially, for BOF/44DDS, the self‐extinguishment happens in 7 s. The fire retardant mechanism confirms that a low heat release rate and heat release capacity as well as a compact char layer occur in the pyrolysis of BOF/DDS. Thus, the BOF/DDS exhibits superior performance over its DGEBA counterparts and meets a wide variety of requirements in engineering.     

Soft-Magnetic High-Entropy AlCoFeMnNi Alloys with Dual-Phase Microstructures Induced by Annealing

The simultaneous enhancement of magnetic and mechanical properties is desirable but challenging for soft-magnetic materials.A fabrication strategy to meet this requirement is therefore in high demand.Herein,bulk equiatomic dual-phase AlCoFeMnNi high-entropy alloys were fabricated via a magnetic levitation induction melting and casting process followed by annealing at 700-1000℃,and their microstructures as well as mechanical and magnetic properties were investigated.The as-cast alloy possessed a single metastable B2-ordered solid solution that decomposed upon annealing into a dual-phase structure comprising an Al-and Ni-rich body-centered cubic(BCC) matrix and Fe-and Mn-rich face-centered cubic(FCC)precipitates both in the grain interior and along the grain boundaries.The magnetic and mechanical properties were closely related to the relative volume fraction of FCC in the alloy.The FCC volume fraction could be increased by increasing the annealing temperature,thereby offering tunable properties.The optimal annealing temperature for balanced magnetic and mechanical properties was found to be 800℃.The alloy annealed at this temperature had an average BCC grain size of 12±3μm and FCC volume fraction of 41±4%.Correspondingly,the s aturation magnetization and coercivity reached 82.57 Am~2/kg and 433 A/m,respectively.The compressive yield strength and fracture strength were 1022 and 2539 MPa,respectively,and the plasticity was 33%.Owing to its adjustable microstructure and properties,the AlCoFeMnNi alloy has potential for use as a multi-functional soft-magnetic material.     

Fine-tuned,molecular-composite,organosilica membranes for highly efficient propylene/propane separation via suitable pore size

Fine-tuned, molecular-composite, organosilica membranes were fabricated via the co-condensation of organosilica precursors bis(triethoxysilyl)acetylene (BTESA) and bis(triethoxysilyl)benzene (BTESB). Fourier transform infrared and UV–vis spectra confirmed the co-condensation behaviors of BTESA and BTESB. The evolution of the network structure indicated that the incorporated BTESB decreased the membrane pore size, which was determined by a modified gas translation model according to the steric effect of the phenyl groups. The incorporation of BTESB to BTESA finely tuned the membrane structure and endowed the resultant composite membrane with improved separation properties. The BTESAB 9:1 membrane (molar ratio of BTESA/BTESB was 9:1) exhibited high C₃H₆ permeance at 4.5 × 10⁻⁸ mol m⁻² s⁻¹ Pa⁻¹ and a C₃H₆/C₃H₈ permeance ratio of 33 at 50°C. One of the most important developments of this study involved clearly defining the relationship between membrane pore size and C₃H₆/C₃H₈ separation performance for organosilica membranes in single and binary separation systems.     

Study on the performance of syntactic foam reinforced by hybrid functionalized carbon nanotubes

Hollow glass microspheres (HGMs)/epoxy syntactic foam were reinforced by hybrid functionalized carbon nanotubes that were synthesized by simultaneous covalent and noncovalent functionalization of carbon nanotubes. The effect of hybrid functionalized carbon nanotubes on density, mechanical properties, and water absorption of HGMs/epoxy syntactic foam was studied. The study indicated that the dispersion of carbon nanotubes in epoxy resin can be improved by hybrid functionalization. The compression strength of syntactic foam reinforced by hybrid functionalized carbon nanotubes was significantly enhanced. The maximum compressive strength of syntactic foam corresponding to chitosan modified carbon nanotubes approached 60 MPa. Hybrid functionalized carbon nanotubes had little effect on the water absorption ability of syntactic foam, and was less than 1%. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48586.     

基于工业机器人的液压支架导向套柔性制造系统

自动化技术在小批量多品种的产品制造中，存在兼容难、换产时间长、人工干预多等问题，导致生产线难以高效率运行。设计的柔性制造系统，在充分分析了导向套不同结构、不同规格的基础上，以一套六关节机器人和行走地轨作为物流搬运设备，同时负责3台数控设备、自动辊道上料设备、自动堆垛下料设备、翻转机构、打标机构及抽检机构的上下料，并通过使用机器人双工位卡爪、机床六爪卡盘、自动刀补等卡具及技术，实现了一键换产，极大提高了制造系统的柔性。     

自保护药芯焊丝明弧堆焊Fe-Cr-C-B-W合金的组织及性能

采用自保护药芯焊丝明弧堆焊技术制备五组不同钨含量的Fe-Cr-C-B-W合金. 借助金相显微镜、扫描电子显微镜、X射线衍射仪、洛氏硬度计和磨损试验机分析堆焊合金的组织及性能. 结果表明，合金的显微组织由马氏体、残余奥氏体、M₇(C,B)₃，M₃(C,B)，Fe₃W₃C和WC组成. 大部分钨元素被迁移到晶界生成了比WC稳定性更好的Fe₃W₃C缺碳复合相，堆焊层中没有典型的初生WC硬质相颗粒生成. 随着钨添加量的增多，共晶硬质相M₇(C,B)₃，M₃(C,B)和Fe₃W₃C随之增多，间距减小，呈连续网状均匀分布. 当钨的添加量为12%时，堆焊层的耐磨性达到最佳.